Appendix E: Schedule 2 - List of Dangerous Goods

Legend

Column 1

Shipping Name and Description — This column gives the shipping names for dangerous goods in alphabetical order within each primary class and within each packing group. The alphabetical order has been determined by ignoring all numerical digits and all lower case letters that precede the first capital letter in the shipping name. The most appropriate designation for the dangerous goods must be selected based on each class, UN number and packing group established per the classification requirements of clause 4.5.

Column 2

Primary Class — This column gives the primary class of the dangerous goods.

Column 3

UN Number — This column gives the UN number assigned to the dangerous goods under the UN system.

Column 4

Packing Group — This column gives the packing groups of the dangerous goods.

Column 5

Special Provisions — This column gives the special provisions that apply to the dangerous goods.

Symbol P

The symbol P used in this schedule means that the handling, offering for transport, and transporting of the dangerous goods by rail is prohibited.

Class 2.1 Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Dimethylamine, anhydrous 2.1 UN1032 5, 6, 8, 63
Ethylamine 2.1 UN1036 4, 63
Ethylene, refrigerated liquid 2.1 UN1038 69
Hydrogen, refrigerated liquid 2.1 UN1966 69
Methane, compressed or Natural gas, compressed, with high methane content 2.1 UN1971 5, 8, 9
Methane, refrigerated liquid or natural gas, refrigerated liquid, with high methane content 2.1 UN1972 69
Methylacetylene and propadiene mixture, stabilized 2.1 UN1060 4, 29, 63
Methylamine, anhydrous 2.1 UN1061 5, 6, 8, 63
Methyl chloride (R40) 2.1 UN1063 5, 6, 8, 63
Petroleum gases, liquefied 2.1 UN1075 4, 61, 63, 77
Vinyl chloride, stabilized 2.1 UN1086 4, 29, 63
Vinyl fluoride, stabilized 2.1 UN1860 5, 58, 59, 63
Vinyl methyl ether, stabilized 2.1 UN1087 4, 29, 63
Dangerous Goods of Class 2.1, not listed above, non-cryogenic 2.1 4, 63

Class 2.2 Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Air, refrigerated liquid 2.2 UN1003 70
Ammonia solutions, relative density less than 0.880 at 15°C (59°F) in water, with more than 35% but not more than 50% ammonia 2.2 UN2073 5, 8, 9
Argon, refrigerated liquid 2.2 UN1951 70
Carbon dioxide, refrigerated liquid 2.2 UN2187 5, 55, 56
Gases, refrigerated liquid, n.o.s. 2.2 UN3158 70
Helium, refrigerated liquid 2.2 UN1963 70
Krypton, refrigerated liquid 2.2 UN1970 70
Neon, refrigerated liquid 2.2 UN1913 70
Nitrogen, compressed 2.2 UN1066 5, 8, 9
Nitrogen, refrigerated liquid 2.2 UN1977 70
Nitrous oxide, refrigerated liquid 2.2 UN2201 5, 14, 55, 56
Oxygen, refrigerated liquid 2.2 UN1073 70
Sulphur hexafluoride 2.2 UN1080 4, 84
Xenon, refrigerated liquid 2.2 UN2591 70
Dangerous Goods of Class 2.2, not listed above, non-cryogenic 2.2 4

Class 2.3 Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Ammonia, anhydrous 2.3 UN1005 5, 6, 8, 9, 60, 61, 75, 79, 80, 81, 83
Ammonia solutions, relative density less than 0.880 at 15°C (59°F) in water, with more than 50% ammonia 2.3 UN3318 5, 6, 8, 9, 60, 75, 79, 80, 81, 83
Boron trichloride 2.3 UN1741 5, 6, 17, 19, 74
Boron trifluoride, compressed 2.3 UN1008 4, 17, 19, 73
Chlorine 2.3 UN1017 5, 6, 19, 51, 64, 73, 83
Chloropicrin and methyl bromide mixture 2.3 UN1581 4, 17, 19, 73
Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone B 2.3 4, 19, 73, 82, 83
Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone C 2.3 4, 17, 19, 74, 80, 83
Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone D 2.3 4, 17, 19, 75, 80, 81, 83
Dinitrogen tetroxide, or Nitrogen dioxide 2.3 UN1067 5, 7, 15, 19, 30, 40, 72, 80, 83
Ethylene oxide or Ethylene oxide, with nitrogen 2.3 UN1040 11, 75, 80, 83
Hydrogen chloride, refrigerated liquid 2.3 UN2186 5, 14, 57, 62, 74, 83
Hydrogen sulphide 2.3 UN1053 5, 7, 17, 19, 63, 65, 73, 83
Methyl bromide 2.3 UN1062 5, 6, 19, 74, 80, 83
Methylchlorosilane 2.3 UN2534 4, 17, 19, 63, 73
Methyl mercaptan 2.3 UN1064 5, 6, 15, 19, 63, 74, 80, 83
Nitrosyl chloride 2.3 UN1069 5, 6, 19, 52, 53, 74, 80, 83
Phosgene 2.3 UN1076 6, 15, 38, 72
Sulphur dioxide, liquefied or Sulphur dioxide 2.3 UN1079 5, 7, 19, 51, 74, 80, 83
Sulphuryl fluoride 2.3 UN2191 5, 54, 75
Trifluoroacetyl chloride 2.3 UN3057 4, 17, 19, 73
Trifluorochloroethylene, stabilized 2.3 UN1082 4, 19, 63, 74
Dangerous Goods of Class 2.3, not listed above 2.3 P

Class 3 Packing Group I Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Acetaldehyde 3 UN1089 I 3, 21
Acrylonitrile, stabilized 3 UN1093 I 3, 17
Allyl chloride 3 UN1100 I 3, 66
tert-Butyl isocyanate 3 UN2484 I 5, 7, 17, 19
Carbon disulphide 3 UN1131 I 3, 21
Chloroprene, stabilized 3 UN1991 I 3, 36
Dimethylhydrazine, symmetrical or 1,2-Dimethylhydrazine 3 UN2382 I 4, 17, 19
Ethyl isocyanate 3 UN2481 I 5, 7, 17, 19, 44, 72
Flammable liquid, n.o.s. 3 UN1993 I 3
Isopropyl isocyanate 3 UN2483 I 5, 7, 17, 19, 44, 72
Methacrylonitrile, stabilized 3 UN3079 I 4, 17, 19, 44, 73
Methoxymethyl isocyanate 3 UN2605 I 5, 7, 17, 19, 44, 72
Methyltrichlorosilane 3 UN1250 I 3, 14
Organochlorine pesticide, liquid, flammable, toxic, flash point less than 23°C (73°F) 3 UN2762 I 3, 66
Petroleum crude oil 3 UN 1267 I 3
Petroleum sour crude oil, flammable, toxic 3 UN 3494 I 3
n-Propyl isocyanate 3 UN2482 I 5, 7, 17, 19
Vinyltrichlorosilane, stabilized 3 UN1305 I 3, 14
Dangerous Goods of Class 3, Packing Group I, not listed above 3 I 3

Class 3 Packing Group II Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Alcohols, n.o.s. 3 UN 1987 II 3
1,1-Dichloroethane 3 UN2362 II 3, 66
1,2-Dichloroethylene 3 UN1150 II 3, 66
Ethanol and gasoline mixture, with more than 10 percent ethanol 3 UN 3475 II 3
Ethylene dichloride 3 UN1184 II 3, 66
Flammable liquid, n.o.s. 3 UN1993 II 3
Isobutyl isocyanate 3 UN2486 II 5, 7, 17, 19, 44, 72
4-Methylmorpholine or n-Methylmorpholine 3 UN2535 II 3, 14
Organochlorine pesticide, liquid, flammable, toxic, flashpoint less than 23°C (73°F) 3 UN2762 II 3, 66
Petroleum crude oil 3 UN 1267 II 3
Petroleum sour crude oil, flammable, toxic 3 UN 3494 II 3
Dangerous Goods of Class 3, Packing Group II, not listed above 3 II 3

Class 3 Packing Group III Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Alcohols, n.o.s. 3 UN 1987 III 3, 12
Chlorobenzene 3 UN1134 III 3, 66
Elevated temperature liquid, flammable, n.o.s., with flash point above 60.5°C (141°F), at or above its flashpoint 3 UN3256 III 67
Flammable liquid, n.o.s. 3 UN1993 III 3, 12
Petroleum crude oil 3 UN 1267 III 3, 12
Petroleum sour crude oil, flammable, toxic 3 UN 3494 III 3
Dangerous Goods of Class 3, Packing Group III, not listed above 3 III 3, 12
Dangerous Goods of Class 4.1, Packing Group I 4.1 I P

Class 4.1 Packing Group II Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Aluminum powder, coated 4.1 UN1309 II 1
Cerium, slabs, ingots or rods 4.1 UN1333 II 1
Ferrocerium 4.1 UN1323 II 1
Flammable solid, corrosive, organic, n.o.s. 4.1 UN2925 II 1
Flammable solid, organic, n.o.s. 4.1 UN1325 II 1
Flammable solid, toxic, organic, n.o.s. 4.1 UN2926 II 3
Lead phosphite, dibasic 4.1 UN2989 II 1
Metal hydrides, flammable, n.o.s. 4.1 UN3182 II 1
Metal powder, flammable, n.o.s. 4.1 UN3089 II 1
Phosphorus sesquisulphide, free from yellow and white phosphorus 4.1 UN1341 II 1
Rubber scrap or Rubber shoddy, powdered or granulated, not greater than 840 mm and rubber content greater than 45% 4.1 UN1345 II 1
Solids containing flammable liquid, n.o.s. 4.1 UN3175 II 1
Titanium hydride 4.1 UN1871 II 2
Dangerous Goods of Class 4.1, Packing Group II, not listed above 4.1 II P

Class 4.1 Packing Group III Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Aluminum powder, coated 4.1 UN1309 III 1
Aluminum resinate 4.1 UN2715 III 1
Borneol 4.1 UN1312 III 1
Camphor, synthetic 4.1 UN2717 III 1
Cobalt naphthenates, powder 4.1 UN2001 III 1
Dicyclohexylammonium nitrite 4.1 UN2687 III 1
Flammable solid, corrosive, organic, n.o.s. 4.1 UN2925 III 3
Flammable solid, organic, n.o.s. 4.1 UN1325 III 1
Flammable solid, toxic, organic, n.o.s. 4.1 UN2926 III 3
Hexamethylenetetramine 4.1 UN1328 III 1
Lead phosphite, dibasic 4.1 UN2989 III 1
Magnesium or Magnesium alloys, with more than 50% magnesium, in pellets, turnings or ribbons 4.1 UN1869 III 1
Manganese resinate 4.1 UN1330 III 1
Metaldehyde 4.1 UN1332 III 1
Metal hydrides, flammable, n.o.s. 4.1 UN3182 III 1
Metal powder, flammable, n.o.s. 4.1 UN3089 III 1
Naphthalene, crude or Naphthalene, refined 4.1 UN1334 III 1
Naphthalene, molten 4.1 UN2304 III 2
Nitronaphthalene 4.1 UN2538 III 1
Paraformaldehyde 4.1 UN2213 III 1
Silicon powder, amorphous 4.1 UN1346 III 1
Sulphur 4.1 UN1350 III 1, 2
Sulphur, molten 4.1 UN2448 III 67
Titanium sponge granules or Titanium sponge powders 4.1 UN2878 III 1
Zinc resinate 4.1 UN2714 III 1
Dangerous Goods of Class 4.1, Packing Group III, not listed above 4.1 III P

Class 4.2 Packing Group I Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Organometallic substance, solid, pyrophoric, water-reactive 4.2 UN 3393 I 4,18
Organometallic substance, liquid, pyrophoric, water-reactive 4.2 UN 3394 I 4, 17, 18
Phosphorus white, molten 4.2 UN2447 I 3, 17, 25
Phosphorus, white or Phosphorus, yellow, dry or Phosphorous, yellow, in solution or Phosphorous, yellow, underwater 4.2 UN1381 I 3, 17, 25
Pyrophoric liquid, organic, n.o.s. 4.2 UN2845 I 4, 18
Titanium powder, dry 4.2 UN2546 I 3
Dangerous Goods of Class 4.2, Packing Group I, not listed above 4.2 I P

Class 4.2 Packing Group II Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Carbon, animal or vegetable origin 4.2 UN1361 II 3
Potassium sulphide, anhydrous or Potassium sulphide, with less than 30% water of crystallization 4.2 UN1382 II 2, 21
Self-heating solid, corrosive, organic, n.o.s. 4.2 UN3126 II 2
Self-heating solid, organic, n.o.s. 4.2 UN3088 II 2
Sodium dithionite or Sodium hydrosulphite 4.2 UN1384 II 2
Sodium methylate 4.2 UN1431 II 2
Sodium sulphide, anhydrous or Sodium sulphide, with less than 30% water of crystallization 4.2 UN1385 II 2
Titanium powder, dry 4.2 UN2546 II 2
Dangerous Goods of Class 4.2, Packing Group II, not listed above 4.2 II P

Class 4.2 Packing Group III Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Carbon, activated 4.2 UN1362 III 2
Carbon, animal or vegetable origin 4.2 UN1361 III 2
Copra 4.2 UN1363 III 2
Fibres or Fabrics, animal or vegetable or synthetic, n.o.s., with oil 4.2 UN1373 III 2
Hafnium powder, dry 4.2 UN2545 III 2
Iron oxide, spent or Iron sponge, spent, obtained from hydrocarbon gas purification 4.2 UN1376 III 1, 22
Seed cake, with more than 1.5% oil and not more than 11% moisture 4.2 UN1386 III 2
Seed cake, with not more than 1.5% oil and not more than 11% moisture 4.2 UN2217 III 2
Self-heating solid, corrosive, organic, n.o.s. 4.2 UN3126 III 3
Self-heating solid, organic, n.o.s. 4.2 UN3088 III 2
Self-heating solid, toxic, organic, n.o.s. 4.2 UN3128 III 3
Titanium powder, dry 4.2 UN2546 III 2
Zirconium scrap 4.2 UN1932 III 1
Dangerous Goods of Class 4.2, Packing Group III, not listed above 4.2 III P

Class 4.3 Packing Group I Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Aluminum phosphide 4.3 UN1397 I 3
Boron trifluoride dimethyl etherate 4.3 UN2965 I 3
Calcium carbide 4.3 UN1402 I 2, 34, 37
Ethyldichlorosilane 4.3 UN1183 I 4
Magnesium powder or Magnesium alloys, powder 4.3 UN1418 I 4, 35
Methyldichlorosilane 4.3 UN1242 I 3, 14
Methyl magnesium bromide in ethyl ether 4.3 UN1928 I 3
Potassium 4.3 UN2257 I 4, 26
Potassium, metal alloys 4.3 UN1420 I 4, 26
Potassium sodium alloys 4.3 UN1422 I 4, 26
Rubidium 4.3 UN1423 I 3, 13
Sodium 4.3 UN1428 I 5, 41
Trichlorosilane 4.3 UN1295 I 4
Dangerous Goods of Class 4.3, Packing Groups I, not listed above 4.3 I P

Class 4.3 Packing Group II Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Aluminum carbide 4.3 UN1394 II 3
Aluminum ferrosilicon powder 4.3 UN1395 II 3
Aluminum smelting by-products or Aluminum remelting by-products 4.3 UN3170 II 3, 78
Barium 4.3 UN1400 II 2
Calcium carbide 4.3 UN1402 II 2, 34, 37
Magnesium powder or Magnesium alloys, powder 4.3 UN1418 II 2, 35
Magnesium silicide 4.3 UN2624 II 2
Phosphorus pentasulphide, free from yellow and white phosphorus 4.3 UN1340 II 3, 37
Dangerous Goods of Class 4.3, Packing Groups II, not listed above 4.3 II P

Class 4.3 Packing Group III Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Aluminum smelting by-products or Aluminum remelting by-products 4.3 UN3170 III 3, 78
Aluminum silicon powder, uncoated 4.3 UN1398 III 2
Calcium cyanamide, with more than 0.1% Calcium carbide 4.3 UN1403 III 2
Calcium manganese silicon 4.3 UN2844 III 2
Ferrosilicon, with 30% or more but less than 90% silicon 4.3 UN1408 III 1
Magnesium granules, coated, particle size not less than 149 mm 4.3 UN2950 III 1
Magnesium powder or Magnesium alloys, powder 4.3 UN1418 III 2, 35
Dangerous Goods of Class 4.3, Packing Group III, not listed above 4.3 III P

Class 5.1 Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Ammonium nitrate, liquid, hot concentrated solution 5.1 UN2426 3

Class 5.1 Packing Group I Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Bromine pentafluoride 5.1 UN1745 I 5, 7, 17, 19, 44, 72
Bromine trifluoride 5.1 UN1746 I 4, 17, 19, 44, 73
Hydrogen peroxide, stabilized or Hydrogen peroxide, aqueous solutions, stabilized, with more than 60% hydrogen peroxide 5.1 UN2015 I 3, 32, 47
Iodine pentafluoride 5.1 UN2495 I 3
Oxidizing solid, corrosive, n.o.s. 5.1 UN3085 I 3
Oxidizing solid, n.o.s. 5.1 UN1479 I 3
Dangerous Goods of Class 5.1, Packing Group I, not listed above 5.1 I P

Class 5.1 Packing Group II Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water 5.1 UN2880 II 1
Chlorate and borate mixture 5.1 UN1458 II 1
Chlorate and magnesium chloride mixture 5.1 UN1459 II 1
Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts 5.1 UN2465 II 1
Hydrogen peroxide, aqueous solution, with more than 40% but not more than 60% hydrogen peroxide, stabilized, as necessary 5.1 UN2014 II 3, 32, 47
Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 40% hydrogen peroxide, stabilized, as necessary 5.1 UN2014 II 3, 32
Potassium chlorate, aqueous solution 5.1 UN2427 II 2
Potassium nitrate and sodium nitrite mixture 5.1 UN1487 II 46
Sodium chlorate 5.1 UN1495 II 1
Sodium chlorate, aqueous solution 5.1 UN2428 II 2, 14
Dangerous Goods of Class 5.1, Packing Group II, not listed above 5.1 II 3
Dangerous Goods of Class 5.1, Packing Group II, Solids, not listed above, having no subsidiary class other than Class 9 5.1 II 1

Class 5.1 Packing Group III Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Dangerous Goods of Class 5.1, Packing Group III, Liquids 5.1 III 2
Dangerous Goods of Class 5.1, Packing Group III, Solids 5.1 III 1

Class 5.2 Packing Group I Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Dangerous Goods of Class 5.2, Packing Group I 5.2 I P

Class 5.2 Packing Group II Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Dangerous Goods of Class 5.2, Packing Group II 5.2 II P

Class 5.2 Packing Group III Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Dangerous Goods of Class 5.2, Packing Group III 5.2 III P

Class 6.1 Packing Group I Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Acetone cyanohydrin, stabilized 6.1 UN1541 I 4, 7, 17, 19, 44, 45, 73
Acrolein, stabilized 6.1 UN1092 I 5, 7, 17, 19, 28, 44, 72
Allyl alcohol 6.1 UN1098 I 4, 17, 19, 44, 73
Allylamine 6.1 UN2334 I 4, 17, 19, 44, 73
Allyl chloroformate 6.1 UN1722 I 4, 17, 19, 44, 73
Arsenic trichloride 6.1 UN1560 I 4, 17, 19, 44, 73
n-Butyl isocyanate 6.1 UN2485 I 4, 17, 19, 44, 73
tert-Butyl isocyanate 6.1 UN2484 I 5, 7, 17, 19, 44, 72
Chloroacetone, stabilized 6.1 UN1695 I 4, 17, 19, 44, 73
Chloroacetyl chloride 6.1 UN1752 I 4, 16, 17, 19, 44, 73
2-Chloroethanal 6.1 UN2232 I 4, 17, 19, 44, 73
Chloropicrin 6.1 UN1580 I 4, 15, 17, 19, 44, 73
Crotonaldehyde, stabilized 6.1 UN1143 I 4, 17, 19, 44, 73
Cyclohexyl isocyanate 6.1 UN2488 I 4, 17, 19, 44, 73
Diketene, stabilized 6.1 UN2521 I 4, 17, 19, 44, 73
Dimethylhydrazine, symmetrical 6.1 UN2382 I 4, 17, 19, 44, 73
Dimethylhydrazine, unsymmetrical 6.1 UN1163 I 4, 15, 17, 19, 44, 73
Dimethyl sulphate 6.1 UN1595 I 4, 17, 19, 44, 73
Ethyl chloroformate 6.1 UN1182 I 4, 17, 19, 44, 73
Ethyldichloroarsine 6.1 UN1892 I 4, 17, 19, 44, 73
Ethylene chlorohydrin 6.1 UN1135 I 4, 17, 19, 44, 73
Ethylene dibromide 6.1 UN1605 I 4, 17, 19, 44, 73
Ethyleneimine, stabilized 6.1 UN1185 I 5, 7, 17, 19, 44, 72
Hexachlorocyclopentadiene 6.1 UN2646 I 4, 17, 19, 44, 73
Hydrocyanic acid, aqueous solution, with not more than 20% hydrogen cyanide 6.1 UN1613 I 4, 7, 39, 44, 73
Hydrogen cyanide, solution in alcohol, with not more than 45 percent hydrogen cyanide 6.1 UN3294 I 4, 17, 19, 44, 73
Hydrogen cyanide, stabilized, containing less than 3% water 6.1 UN1051 I 5, 7, 39, 44, 48, 72
Iron Pentacarbonyl 6.1 UN1994 I 5, 7, 17, 19, 44, 72
Isopropyl chloroformate 6.1 UN2407 I 4, 17, 19, 44, 73
Methanesulfonyl chloride 6.1 UN3246 I 4, 17, 19, 44, 73
Methyl bromide and ethylene dibromide mixture, liquid 6.1 UN1647 I 4, 17, 19, 44, 73
Methyl chloroformate 6.1 UN1238 I 5, 7, 17, 19, 44, 72
Methyl chloromethyl ether 6.1 UN1239 I 5, 7, 17, 19, 44, 72
2-Methyl-2-heptanethiol 6.1 UN3023 I 4, 17, 19, 44, 73
Methylhydrazine 6.1 UN1244 I 5, 7, 15, 17, 19, 44, 72
Methyl iodide 6.1 UN2644 I 4, 17, 19, 44, 73
Methyl isocyanate 6.1 UN2480 I 5, 7, 17, 19, 44, 72
Methyl isothiocyanate 6.1 UN2477 I 4, 17, 19, 44, 73
Methyl orthosilicate 6.1 UN2606 I 4, 17, 19, 44, 73
Methyl vinyl ketone, stabilized 6.1 UN1251 I 5, 7, 17, 19, 44, 72
Motor fuel antiknock mixture 6.1 UN1649 I 4, 17
Organochlorine pesticide, liquid, toxic 6.1 UN2996 I 3, 66
Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23°C (73°F) 6.1 UN2995 I 3, 66
Organochlorine pesticide, solid, toxic 6.1 UN2761 I 3, 66
Perchloromethyl mercaptan 6.1 UN1670 I 4, 17, 19, 44, 73
Phenylcarbylamine chloride 6.1 UN1672 I 4, 17, 19, 44, 73
Phenyl isocyanate 6.1 UN2487 I 4, 17, 19, 44, 73
Phenyl mercaptan 6.1 UN2337 I 4, 17, 19, 44, 73
Phosphorus trichloride 6.1 UN1809 I 4, 17, 19, 22, 44, 73
Potassium cyanide 6.1 UN1680 I 3, 42
n-Propyl chloroformate 6.1 UN2740 I 4, 17, 19, 44, 73
n-Propyl isocyanate 6.1 UN2482 I 5, 7, 17, 19, 44, 72
Sodium cyanide 6.1 UN1689 I 3, 42
Sulphuryl chloride 6.1 UN1834 I 5, 7, 14, 17, 19, 44, 72
Thiophosgene 6.1 UN2474 I 4, 17, 19, 44, 73
Titanium tetrachloride 8 UN1838 I 4, 15, 17, 19, 44, 73
Toxic liquid, flammable, organic, n.o.s. 6.1 UN2929 I 3, 66
Toxic, liquid, organic, n.o.s. 6.1 UN2810 I 3, 66
Toxic, solid, organic, n.o.s. 6.1 UN2811 I 3, 66
Toxic by inhalation, liquid, n.o.s., with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 UN3381 I 5, 7, 17, 19, 44, 72
Toxic by inhalation, liquid, n.o.s., with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 UN3382 I 4, 17, 19, 44, 73
Toxic by inhalation, liquid, flammable, n.o.s., with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 UN3383 I 5, 7, 17, 19, 44, 72
Toxic by inhalation, liquid, flammable, n.o.s., with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 UN3384 I 4, 17, 19, 44, 73
Toxic by inhalation, liquid, water reactive, n.o.s., with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 UN3385 I 5, 7, 17, 19, 44, 72
Toxic by inhalation, liquid, water reactive, n.o.s., with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 UN3386 I 4, 17, 19, 44, 73
Toxic by inhalation, liquid, oxidizing, n.o.s., with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 UN3387 I 5, 7, 17, 19, 44, 72
Toxic by inhalation, liquid, oxidizing, n.o.s., with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 UN3388 I 4, 17, 19, 44, 73
Toxic by inhalation, liquid, corrosive, n.o.s., with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 UN3389 I 5, 7, 17, 19, 44, 72
Toxic by inhalation, liquid, corrosive, n.o.s., with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 UN3390 I 4, 17, 19, 44, 73
Trimethyl acetyl chloride 6.1 UN2438 I 4, 17, 19, 44, 73
Dangerous Goods of Class 6.1, Packing Group I, Liquids, not listed above 6.1 I 3
Dangerous Goods of Class 6.1, Packing Group I, Solids, not listed above 6.1 I 2

Class 6.1 Packing Group II Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Allyl isothiocyanate, stabilized 6.1 UN1545 II 4, 17, 19
Benzyl chloride 6.1 UN1738 II 3, 43
Bromoacetone 6.1 UN1569 II P
n-Butyl chloroformate 6.1 UN2743 II 4, 17, 19, 44, 73
Carbon tetrachloride 6.1 UN1846 II 3, 66
Chloroacetonitrile 6.1 UN2668 II 4, 17, 19, 44, 73
Chloroanilines, solid 6.1 UN2018 II 3, 66
Chlorocresols solution 6.1 UN 2669 II 3, 66
Chlorocresols, solid 6.1 UN3437 II 3, 66
Dibromochloropropanes 6.1 UN2872 II 3, 66
Dichloroisopropyl ether 6.1 UN2490 II 3, 66
Ethylene chlorohydrin 6.1 UN1135 II 4, 17, 19
Organochlorine pesticide, liquid, toxic 6.1 UN2996 II 3, 66
Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23°C (73°F) 6.1 UN2995 II 3, 66
Organochlorine pesticide, solid, toxic 6.1 UN2761 II 3, 66
Pentachloroethane 6.1 UN1669 II 3, 66
Phenol, molten 6.1 UN2312 II 3, 66
Toxic liquid, flammable, organic, n.o.s. 6.1 UN2929 II 3, 66
Toxic liquid, organic, n.o.s. 6.1 UN2810 II 3, 66
Toxic solid, organic, n.o.s. 6.1 UN2811 II 3, 66
Toluidines, liquid 6.1 UN1708 II 2
Dangerous Goods of Class 6.1, Packing Group II, Liquids, not listed above 6.1 II 3
Dangerous Goods of Class 6.1, Packing Group II, Solids, not listed above 6.1 II 2

Class 6.1 Packing Group III Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Bromoform 6.1 UN2515 III 3, 66
Chlorocresols solution 6.1 UN 2669 III 3, 66
Chloroform 6.1 UN1888 III 3, 66
Chlorophenols, liquid 6.1 UN2021 III 3, 66
Dibromochloropropanes 6.1 UN2872 III 3, 66
Dibromomethane 6.1 UN2664 III 3, 66
o-Dichlorobenzene 6.1 UN1591 III 3, 66
Dichloromethane 6.1 UN1593 III 3, 66
Hexachlorobenzene 6.1 UN2729 III 3, 66
Hexachlorobutadiene 6.1 UN2279 III 3, 66
Hexachlorophene 6.1 UN2875 III 3, 66
Organochlorine pesticide, liquid, toxic 6.1 UN2996 III 3, 66
Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23°C (73°F) 6.1 UN2995 III 3, 66
Organochlorine pesticide, solid, toxic 6.1 UN2761 III 3, 66
Tetrachloroethylene 6.1 UN1897 III 3, 66
Toxic liquid, organic, n.o.s. 6.1 UN2810 III 3, 66
Toxic solid, organic, n.o.s. 6.1 UN2811 III 3, 66
1,1,1-Trichloroethane 6.1 UN2831 III 3, 66
Trichloroethylene 6.1 UN1710 III 3, 66
Dangerous Goods of Class 6.1, Packing Group III, Liquids, not listed above 6.1 III 2
Dangerous Goods of Class 6.1, Packing Group III, Solids, not listed above 6.1 III 1
Dangerous Goods of Class 6.1, Packing Group III, not listed above, with a subsidiary classification other than 9 6.1 III 3

Class 8 Packing Group I Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Boron tribromide 8 UN2692 I 4, 17, 19, 44, 73
Bromine or Bromine solution 8 UN1744 I 10, 17, 72
Bromine solution 8 UN1744 I 10, 17, 73
Chlorosulphonic acid, with or without sulphur trioxide 8 UN1754 I 4, 17, 19, 44, 73
Chromosulphuric acid 8 UN2240 I 3, 14
Fluorosulphonic acid 8 UN1777 I 3, 14
Hydrazine, anhydrous 8 UN2029 I 3, 21, 32
Hydrazine, aqueous solution, with more than 37% hydrazine, by mass 8 UN2030 I 3, 21, 32
Hydrazine, aqueous solution, flammable with more than 37% hydrazine, by mass 8 UN2030 I 3, 21, 32
Hydrofluoric acid and sulphuric acid mixture 8 UN1786 I 3, 20, 23
Hydrofluoric acid solution, more than 60% hydrogen fluoride 8 UN1790 I 3, 20, 23
Hydrogen fluoride, anhydrous 8 UN1052 I 4, 15, 44, 74
Nitrating acid mixtures, more than 50% nitric acid 8 UN1796 I 3
Nitric acid, other than red fuming, with more than 70% nitric acid 8 UN2031 I 3, 32
Nitric acid, red, fuming 8 UN2032 I 4, 17, 44, 73
Sulphuric acid, fuming, greater than or equal to 30% free sulphur trioxide 8 UN1831 I 4, 17, 19, 44, 73
Sulphuric acid, fuming, less than 30% free sulphur trioxide 8 UN1831 I 3, 49
Sulphur trioxide, stabilized 8 UN1829 I 4, 17, 19, 31, 44, 73
Thionyl chloride 8 UN1836 I 3, 14
Dangerous Goods of Class 8, Packing Group I, not listed above 8 I 3

Class 8 Packing Group II Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Allyltrichlorosilane, stabilized 8 UN1724 II 3, 14
Amyltrichlorosilane 8 UN1728 II 3, 14
Battery fluid, acid or Sulphuric acid, with not more than 51% acid 8 UN2796 II 3, 20
Boron trifluoride acetic acid complex 8 UN1742 II 3, 14
Butyltrichlorosilane 8 UN1747 II 3, 14
Chlorophenyltrichlorosilane 8 UN1753 II 3, 14
Dichloroacetyl chloride 8 UN1765 II 3, 14
Dichlorophenyltrichlorosilane 8 UN1766 II 3, 14
Diethyldichlorosilane 8 UN1767 II 3, 14
Diphenyldichlorosilane 8 UN1769 II 4, 8
Dodecyltrichlorosilane 8 UN1771 II 3, 14
Ethyl chlorothioformate 8 UN2826 II 4, 17, 19, 44, 73
Fluoroboric acid 8 UN1775 II 3, 20
Fluosilicic acid 8 UN1778 II 3, 20
Formic acid, with more than 85% acid by mass 8 UN1779 II 3, 27
Hexadecyltrichlorosilane 8 UN1781 II 3, 14
Hexyltrichlorosilane 8 UN1784 II 3, 14
Hydrazine, aqueous solution, with more than 37% hydrazine, by mass 8 UN2030 II 3, 21, 32
Hydrobromic acid 8 UN1788 II 3, 20
Hydrochloric acid 8 UN1789 II 3, 20
Hydrofluoric acid solution, not more than 60% hydrogen fluoride 8 UN1790 II 3, 20
Hypochlorite solution 8 UN1791 II 3, 20
Iodine monochloride 8 UN1792 II 3, 14
Nitrating acid mixtures, not more than 50% nitric acid 8 UN1796 II 3
Nitric acid, other than red fuming, with not more than 70% nitric acid 8 UN2031 II 3, 32
Nonyltrichlorosilane 8 UN1799 II 3, 14
Octadecyltrichlorosilane 8 UN1800 II 3, 14
Octyltrichlorosilane 8 UN1801 II 3, 14
Phenylphosphorus dichloride 8 UN2798 II 3, 20
Phenylphosphorus thiodichloride 8 UN2799 II 3, 20
Phenyltrichlorosilane 8 UN1804 II 3, 14
Phosphorus oxybromide 8 UN1939 II 1, 16
Phosphorus oxybromide, molten 8 UN2576 II 3, 16
Phosphorus oxychloride 8 UN1810 II 4, 17, 19, 44, 73
Phosphorus tribromide 8 UN1808 II 3, 24
Propyltrichlorosilane 8 UN1816 II 3, 14
Silicon tetrachloride 8 UN1818 II 3, 14
Sulphuric acid, spent 8 UN1832 II 3, 49, 50
Sulphuric acid, with more than 51% acid 8 UN1830 II 3, 49, 50
Thiophosphoryl chloride 8 UN1837 II 3, 16, 24
Trichloroacetyl chloride 8 UN2442 II 4, 17, 19, 44, 73
Vanadium oxytrichloride 8 UN2443 II 3, 21
Dangerous Goods of Class 8, Packing Group II, Liquids, not listed above 8 II 3
Dangerous Goods of Class 8, Packing Group II, Solids, not listed above 8 II 1

Class 8 Packing Group III Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Ferric chloride solution 8 UN2582 III 2, 20
Hydrazine, aqueous solution, with more than 37% hydrazine, by mass 8 UN2030 III 3, 21, 32
Hydrobromic acid 8 UN1788 III 3, 20
Hydrochloric acid 8 UN1789 III 3, 20
Dangerous Goods of Class 8, Packing Group III, Liquids, not listed above 8 III 2
Dangerous Goods of Class 8, Packing Group III, Solids, not listed above 8 III 1

Class 9 Packing Group I Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Dangerous Goods of Class 9, Packing Group I, Liquids 9 I 2
Dangerous Goods of Class 9, Packing Group I, Solids 9 I 1

Class 9 Packing Group II Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Blue asbestos (crocidolite) or Brown asbestos (amosite, mysorite) 9 UN2212 II 1, 71
Polychlorinated biphenyls, Liquids 9 UN2315 II 3, 66
Dangerous Goods of Class 9, Packing Group II, Liquids, not listed above 9 II 2
Dangerous Goods of Class 9, Packing Group II, Solids, not listed above 9 II 1

Class 9 Packing Group III Dangerous Goods

Column 1
Shipping Name and
Description
Column 2
Primary Class
Column 3
UN
Number
Column 4
Packing Group
Column 5
Special Provision
Elevated temperature liquid, n.o.s., at or above 100°C (212°F) and below its flashpoint including molten metals, molten salts, etc. 9 UN3257 III 67
Elevated temperature solid, n.o.s., at or above 240°C (464°F) 9 UN3258 III 68
Environmentally hazardous substance, solid, n.o.s. 9 UN3077 III 1, 33
White asbestos (chrysotile, actinolite, anthophyllite, tremolite) 9 UN2590 III 1, 71
Dangerous Goods of Class 9, Packing Group III, Liquids, not listed above 9 III 2
Dangerous Goods of Class 9, Packing Group III, Solids, not listed above 9 III 1

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