Crude Oil Research

Abstract: Crude Oil Sampling and Testing Methods Literature Review - February 8, 2017

The Transportation of Dangerous Goods Program commissioned a literature review comparing sampling and analysis methods and their appropriateness to a number of Canadian crude oils. Currently there are significant variations in the type of sampling and analysis techniques used for crude oil classification prior to the oil being transported in Canada. A specific sampling method may only be suitable for certain types of crude oils and certain analytical methods. By the same token, for a specific analytical test, one sampling method may work better than another, depending on the type of crude oil. As a result, InnoTech Alberta, a provincial research corporation, undertook this work. The literature survey concluded that sampling into open containers under atmospheric pressure is suitable for collecting samples of dead crude oils, heavy crude oils, and for test methods where the loss of light components will not affect the accuracy of analytical techniques. Sampling under closed conditions should be done whenever there are any concerns about the loss of volatiles and for light oils including condensates, and diluted bitumen. In terms of test methods, those that allow direct sample introduction from a pressurized cylinder into the instrument (such ASTM D8003) and eliminate evaporative losses prior to analysis are preferred. Density and hydrogen sulfide content measurements can also be affected by the loss of volatiles and therefore methods that call for closed sampling are recommended.

Learn More

To obtain a copy of the report, please contact the Safety Research and Analysis Branch, Transportation of Dangerous Goods Directorate, Transport Canada at TDG-RD-TMD@tc.gc.ca.

Abstract - Task 2: Sampling and Analysis Method Evaluation:

The United States (US) Department of Energy (DOE) launched the Crude Oil Characterization Research Study in 2015, with the US Department of Transportation (DOT) and with the Sandia National Laboratories (SNL) serving as technical lead.

Transport Canada is working with US DOE and DOT on this research. Together, they will evaluate whether crude oils transported in North America, including those produced from "tight" formations, exhibit physical or chemical and combustion properties that are distinct from conventional crudes during transportation and handling.

SNL’s comprehensive Crude Oil Characteristics Research Sampling, Analysis and Experiment (SAE) Plan (PDF, 286 KB) makes recommendations it describes as distinct tasks. These tasks describe the research needed to improve understanding of tight crude oil properties, especially as they compare to conventional crude oil properties and relate to transportation.

Task 1, a literature review entitled ‘Review and Evaluate New and Emerging Crude Oil Characterization Data’ is complete; TC did not participate on this task. You can find a report at http://prod.sandia.gov/techlib/access-control.cgi/2015/151823.pdf (PDF, 7.3 MB).

The SAND2017-12482 report (released in December 2017) presents results from Task 2: Sampling and Analysis Method Evaluation.

The aim of Task 2 was to identify commercially available methods that accurately and reproducibly collect and analyze crude oils for vapor pressure and composition, including dissolved gases. The project team selected several sampling and analysis methods, then compared their performance to that of a well-established mobile laboratory system; the current baseline instrument system for the U.S. Strategic Petroleum Reserve Crude Oil Vapor Pressure Program.

Specifically, using crude oil sampled from two specific locations in the US, the experimental matrix evaluated performance for both:

  1. capturing, transporting, and delivering hydrocarbon fluid samples from the field to the analysis laboratory,
  2. analyzing for properties related to composition and volatility of the oil, including true vapor pressure, gas-oil ratio, and dissolved gases and light hydrocarbons.

The report SAND2017-12482 was revised (June 2018) and a new report (SAND2018-5909) “Revision 1 – Winter Sampling” was issued. This report incorporates additional seasonal data and compositional analysis results that have become available since the publication of the prior report, SAND2017-12482, in December 2017.

Going forward, the project team will use methods that performed well in Task 2 in:

  • Task 3 (Combustion Experiments and Modeling)
  • Task 4 (Compositional Analyses of Multiple Crude Types)

You can access the original Task 2 report (SAND 2017-12482 report released in December 2017) at https://www.osti.gov/scitech/biblio/1414422-doe-dot-crude-oil-characterization-research-study-task-test-report-evaluating-crude-oil-sampling-analysis-methods.

You can access the Revision 1 of the Task 2 report (SAND2018-5909, June 2018) at (https://www.osti.gov/biblio/1458999-doe-dot-crude-oil-characterization-research-study-task-test-report-evaluating-crude-oil-sampling-analysis-methods).

If you have any questions or comments about this work, please contact the Safety Research and Analysis Branch, Transportation of Dangerous Goods Directorate, Transport Canada at TDG-RD-TMD@tc.gc.ca.

Abstract: Crude Oil Sampling and Analysis Final Report - August 10, 2015

The July 6, 2013 Lac-Mégantic derailment and other incidents in Canada and the United States have raised many questions about the safe transport of crude oil by rail. They also put a spotlight on the need to further investigate crude oil properties and behaviour.

This report describes the testing the Transportation of Dangerous Goods Directorate has done to assess the composition and properties of crude oils transported by road and rail in Canada. We:

  • Verified the applicability of the current classification requirements described in the Transportation of Dangerous Goods Regulations (TDGR) Part 2, for Class 3, Flammable liquids; and Class 2, Gases.
  • Focussed on assessing other hazards that crude oil may pose during transport.

Study Methods

68 samples of crude oil were collected and analysed. The crude oil was destined for transport by rail or road in Canada and represents a wide range of crude oils from condensates to bitumen, under controlled conditions. We also subjected the samples to a variety of tests including but not limited to:

  • Flash point determination
  • Initial Boiling Point determination (IBP)
  • Reid Vapor Pressure (RVP)
  • True Vapor Pressure (TVP)
  • Compositional analysis and Gas Oil Ratio by gas chromatography (GC)
  • Hydrogen sulphide (H2S) analysis in the vapor phase and flammable gas testing

Research Results

  • The GC method found IBPs that put 56 out of the 68 samples in Packing Group I, the highest hazard group for Class 3 Flammable Liquids.
  • The ASTM D86 method, a commonly used standard for IBP testing of flammable liquids, found IBPs consistently higher than the GC tests.
  • The Report recommends using the method that combines GC data from two ASTM standards (D8003/ D7169) as a more accurate method for determining IBP of crude oil containing light ends (methane, ethane, propane and butane).
  • Most TVP values were above atmospheric pressure (101 kPa) at 50 oC.
  • TVP values were higher than the RVP values for the crude oil samples tested by both methods.
  • Based on compositional analysis, one crude oil sample contained enough amounts of light ends to result in a TVP above 300 kPa at 50 oC, which meets the TDGR's definition of a gas.
  • Vapour phase measurements of H2S ranged from 0-65000 ppm, with 42 of the 68 crude oil samples having values below 1000 ppm.

We performed this testing with Alberta Innovates-Technology Futures (AITF), an Alberta provincial research corporation.

Learn More

To obtain a copy of the report, please contact the Safety Research and Analysis Branch, Transportation of Dangerous Goods Directorate, Transport Canada at TDG-RD-TMD@tc.gc.ca.

UPDATE: Report Annex: Crude Oil Dataset

To support the published report, the crude oil data collected during this project is now available upon demand.

The data set is presented in Microsoft Excel and contains the following information on the samples:

  • Region of origin;
  • Sample type (e.g., heavy oil, condensate, etc.);
  • Sampling method (atmospheric or pressurized);
  • Inbound and outbound mode of transportation (rail, pipeline, truck);
  • Hydrogen sulphide (H2S) concentration in the vapor phase (ppm);
  • Flash point (°C);
  • Water and sediment content (%);
  • Density (kg/m3);
  • Initial Boiling Point (IBP) (°C);
  • Reid Vapor Pressure (RVP) (kPa);
  • True Vapor Pressure (TVP) (kPa);
  • Gas Oil Ratio (m3/m3);
  • Simulated distillation profile; and
  • Compositional analysis (%).

Note: The data set does not name the companies that own or operate the facilities at which we took samples or the exact geographic point of sampling.

To obtain a copy of the data, please contact the Safety Research and Analysis Branch, Transportation of Dangerous Goods Directorate, Transport Canada at TDG-RD-TMD@tc.gc.ca.

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